Keyword Reference

The default values are given as an example below for each keyword of the %cc block.

Keyword descpriptions for %cc block

cc_convergence: Float

Controls the desired convergence criteria for CCSD correlation energy.

cc_convergence 1.0e-10

adc_convergence: Float

adc_convergence  1.0e-6

eom_convergence: Float

eom_convergence 1.0e-6

lambda_convergence: Float

lambda_convergence 1.0e-6

resp_convergence: Float

resp_convergence 1.0e-10

ucc_convergence: Float

ucc_convergence 1.0e-7

NRoots: Integer

NRoots 2

koopmans: Logical

koopmans True

Opt: Logical

Opt False

CCSD2 Logical

CCSD2  False

cc_restart Integer

cc_restart 0

real_ints Logical

real_ints flase

CD_Threshold Float

CD_Threshold 1e-5

scf_guess_read Logical

scf_guess_read False

remove_linear_dependency Logical

remove_linear_dependency False

DoCore Logical

DoCore False

DoCVS Logical

DoCVS False

DoR3CVS Logical

DoR3CVS False

DoR3OPT Logical

DoR3OPT True

Debug Logical

Debug False

DF Logical

DF False

CVSMIN Integer

CVSMIN 0

CVSMAX: Integer

CVSMAX 0

CoreHole Integer

CoreHole 0

initial_eta Float

initial_eta 0.0

ita_step Float

ita_step 0.001

max_ita_iter Integer

max_ita_iter 100

Dolambda Logical

Dolambda False

qed Logical

qed False

Dopertrip Logical

Dopertrip False

lambda_restart Integer

lambda_restart 0

printlevel Integer

printlevel 0

maxcore Integer

maxcore 0

ML Logical

ML False

pct_occ_ex Float

pct_occ_ex 0.0

incore Integer

incore 5

DoADC2 Logical

DoADC2 False

reldipole Logical

reldipole False

DumpEOM Logical

DumpEOM False

DoNataux Logical

DoNataux False

Natauxpct_ex Integer

Natauxpct_ex 100

Natauxthresh Integer

Natauxthresh 0

Natauxthresh_ex Integer

Natauxthresh_ex 100

Natauxthresh_bottleneck Float

Natauxthresh_bottleneck 1e-1

Natauxthresh_ex_bottleneck Float

Natauxthresh_ex_bottleneck 1e-1

nfr_h Integer

nfr_h 3

nfr_p Integer

nfr_p 3

fc Logical

fc False

fc_no Integer

fc_no -1

noact Integer

noact 1

nvact Integer

nvact  1

DoACTCC Logical

DoACTCC False

Gaunt Logical

Gaunt False

Breit Logical

Breit False

ssss Logical

ssss True

custom_basis Integer

custom_basis  None

light_speed Integer

light_speed None

DoLoc Logical

DoLoc False

DIIS Logical

DIIS True

NumProc Integer

NumProc 1

TCutPair Float

TCutPair 1e-5

TCutPNO Float

TCutPNO 1e-6

int_restart Integer

int_restart 0

cis_restart Integer

cis_restart 0

imds_restart Integer

imds_restart []

ext_e Integer

ext_e None

pyberny_flag Integer

pyberny_flag 0

rootno Logical

rootno False

max_space Integer

max_space 100

max_cycle Integer

max_cycle 100

x2c Logical

x2c False

relcc Logical

relcc False

ccsdnat Logical

ccsdnat False

actspace_overide Logical

actspace_overide False

act_cvir Integer

act_cvir None

povo_can Integer

povo_can None

splitfno Logical

splitfno False

runmrcc Logical

runmrcc False

symmetry Logical

symmetry False

symmetry_subgroup

symmetry_subgroup c1

correction Logical

correction False

splitorders Integer

splitorders 1,2,3

mpi Logical

mpi False

scf_guess_read Logical

scf_guess_read False

pic_change Logical

pic_change

remove_linear_dependency Logical

remove_linear_dependency False

povo

povo None

povo_ex

povo_ex None

omega Integer

omega 0

pytranf Logical

pytranf False

dirac_complex Logical

dirac_complex False

plotnat Logical

plotnat False

plotnat_no

plotnat_no []

plotnto Logical

plotnto False

plotnto_no

plotnto_no []

Triplet Logical

Triplet False

DysonOrbPlot Logical

DysonOrbPlot False

exdm Logical

exdm True

tdm Logical

tdm True

z_axis Logical

z_axis False

x_axis Logical

x_axis False

ucc_prop Logical

ucc_prop False

fort Logical

fort True

CD Logical

CD False

ccpert_lambda Logical

ccpert_lambda True

T3 Logical

T3 False

bulksize Integer

bulksize 10

dtype Integer

dtype None

Pembed Logical

Pembed False

shift_e ``Integer ``

shift_e 0

CD_Threshold Float

CD_Threshold 1e-5

active_atoms

active_atoms

cpy Logical

cpy False

cav_frequency Integer

cav_frequency 0

cav_lambda_x Integer

cav_lambda_x None

cav_lambda_y Integer

cav_lambda_y  None

cav_lambda_z Integer

cav_lambda_z  None

x2c_type

x2c_type  x2camf

By default, the x2c_type is x2camf. For model potential, the keyword is x2c_type x2cmp. The spin-free x2c1e and spin-orbit x2c1e can be requested via x2c_type sf1e and x2c_type 1e.